Nitroxide polymer networks formed by Michael addition: on site-cured electrode-active organic coating.

نویسندگان

  • Takeshi Ibe
  • Rainer B Frings
  • Artur Lachowicz
  • Soichi Kyo
  • Hiroyuki Nishide
چکیده

Highly and homogeneously crosslinked poly(beta-ketoester) networks densely bearing robust nitroxide radicals were prepared via a click-type and stepwise Michael polyaddition. A half-battery cell composed of the thermally-cured radical network coatings displayed a rapid, reversible, and almost stoichiometric redox-activity even with a thickness of ca. 10 mum, which may be applicable as the electrode of organic-based rechargeable devices.

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عنوان ژورنال:
  • Chemical communications

دوره 46 20  شماره 

صفحات  -

تاریخ انتشار 2010